 | Steve Martin | | Self - Introductory Host |
| Itzhak Perlman | | Self - Host (segment "Pines of Rome") |
| Quincy Jones | | Self - Host (segment "Rhapsody in Blue") |
| Bette Midler | | Self - Host (segment "Piano Concerto No. 2, Allegro, Opus 102") |
| James Earl Jones | | Self - Host (segment "Carnival of the Animals") |
| Penn Jillette | | Self - Host (segment "The Sorcerer's Apprentice") |
| Teller | | Self - Host (segment "The Sorcerer's Apprentice") |
| James Levine | | Self - Host (segment "Pomp and Circumstance"), Conductor (Chicago Symphony Orchestra) |
| Angela Lansbury | | Self - Host (segment "Firebird Suite - 1919 Version") |
| Wayne Allwine | | Mickey Mouse (segment "Pomp and Circumstance") (voice) |
| Tony Anselmo | | Donald Duck (segment "Pomp and Circumstance") (voice) |
| Russi Taylor | | Daisy Duck (segment "Pomp and Circumstance") (voice) |
| Chicago Symphony Orchestra | | Themselves |
| Guy Richardson | | Animator |
